Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges.

نویسندگان

  • Ana M García-Deibe
  • Cristina Portela-García
  • Matilde Fondo
  • Antonio J Mota
  • Jesús Sanmartín-Matalobos
چکیده

A decanuclear Cd complex has been found as a carbonate-containing capsule. The structure strongly resembles a ten-blade waterwheel with a central carbonate ligand surrounded by two superimposed Cd(5)O(5) crowns with a pentagonal antiprism-like disposition. The capsule is doubly capped by two pentadentate perchlorate anions.

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عنوان ژورنال:
  • Chemical communications

دوره 48 79  شماره 

صفحات  -

تاریخ انتشار 2012